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Title |
Visible-Light Photoredox-Catalyzed α-Regioselective Conjugate Addition of Allyl Groups to Activated Alkenes |
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Author list |
Gontala, Arjun and Woo, Sang Kook |
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Publication date |
2020/08 |
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Citation information |
Advanced Synthesis & Catalysis, 2020, 362, 3223. |
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DOI |
https://doi.org/10.1002/adsc.202000445 |
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Graphical Abstract |
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Abstract |
The α?regioselective conjugate addition of allyl groups to activated alkenes is a poorly explored area of research. Herein, we report an α?dduct and (E)?somer selective conjugate addition of allylsilanes to activated alkenes by visible?ight photoredox catalysis. The reaction involves allylic radicals that can be generated from allylsilanes through a photoinduced single?lectron transfer mechanism. |
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